The planet reflects much less sunlight than the Moon, on which surface darkness is controlled by the abundance of iron-rich minerals that are known to be rare on Mercury's surface, researchers said.    

Scientists had earlier proposed that Mercury's darkness was due to carbon that gradually accumulated from the impact of comets that travelled into the inner solar system.

Researchers led by Patrick Peplowski of the Johns Hopkins University in US have confirmed that a high abundance of carbon is present at Mercury's surface.

They have also found that, rather than being delivered by comets, the carbon most likely originated deep below the surface in the form of a now-disrupted and buried ancient graphite-rich crust, some of which was later brought to the surface by impact processes after most of Mercury's current crust had formed.

The researchers obtained data from NASA's MESSENGER (Mercury Surface, Space Environment, Geochemistry, and Ranging) spacecraft, the first space mission designed to orbit Mercury.

"We used both neutrons and X-rays to confirm that the dark material is not enriched in iron, in contrast to the Moon where iron-rich minerals darken the surface," said Nittler, who is also Deputy Principal Investigator of the MESSENGER mission.

MESSENGER obtained its data via many orbits on which the spacecraft passed lower than 100 km above the surface of the planet during its last year of operation.

Combining the neutron measurements with other MESSENGER data sets, including X-ray measurements and reflectance spectra, scientists found that Mercury's surface rocks are made up of as much as a few weight per cent graphitic carbon, much higher than on other planets.

Graphite has the best fit to the reflectance spectra, at visible wavelengths, and the likely conditions that produced the material, researchers said.

When Mercury was very young, much of the planet was likely so hot that there was a global 'ocean' of molten magma.

Scientists have suggested that as this magma ocean cooled, most minerals that solidified sank, except graphite, which would have been buoyant and floated to form the original crust of Mercury.

The study was published in the journal Nature Geoscience.

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